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Ozone Nanobubbles combined with electrolysis for chlorine-free treatment of eco-pool

1. Ozone nanobubbles

   * Produce ozone with extremely high dissolution efficiency.
   * Nanobubbles remain suspended for hours to days, increasing ozone contact time.
   * Destroy bacteria, viruses, algae, and organic contaminants.

2. Electrolysis
   Depending on the electrode material, electrolysis can:

   * Generate hydroxyl radicals (•OH)
   * Generate hydrogen peroxide (H₂O₂)
   * Produce oxygen microbubbles
   * Produce small amounts of ozone (with specialized electrodes)
   * Oxidize dissolved contaminants directly at the anode

3. Advanced Oxidation Process (AOP)
   Ozone reacts with electrochemically produced radicals to generate:

   * Hydroxyl radicals (•OH)
   * Superoxide radicals
   * Peroxone-type reactions

These radicals are even stronger oxidants than ozone itself.

 Main benefits

1. Very strong disinfection

The combination attacks microorganisms through multiple mechanisms.

It can inactivate:

* bacteria
* viruses
* fungi
* algae
* protozoa

faster than ozone alone.

Unlike chlorine, ozone and hydroxyl radicals do not rely primarily on chlorination reactions.

 2. Excellent oxidation of body contaminants

Swimmers introduce:

* sweat
* urine
* sunscreen
* cosmetics
* body oils
* lotions
* proteins

These consume chlorine in conventional pools.

Ozone + electrolysis rapidly oxidizes these contaminants into:

* CO₂
* water
* biodegradable compounds

This reduces organic loading.

 3. Nearly eliminates chloramine formation

Chloramines are responsible for:

* strong chlorine smell
* eye irritation
* red eyes
* asthma symptoms
* respiratory irritation

Without chlorine:

there are essentially no chloramines produced.

The pool smells much fresher.

 4. Crystal-clear water

Nanobubbles improve oxidation throughout the entire pool volume.

Benefits include:

* better removal of dissolved organics
* oxidation of color compounds
* improved filtration efficiency
* brighter water

Many users describe ozone-treated water as appearing "sparkling."

 5. Biofilm control

Biofilms form on:

* pipes
* filters
* pool walls
* skimmers

Biofilms protect bacteria from disinfectants.

Ozone nanobubbles can penetrate biofilms more effectively than dissolved ozone because nanobubbles increase ozone transport to surfaces. Electrochemically generated oxidants further weaken the biofilm matrix, making biofilms easier to remove.

 6. Reduced chemical storage

Without chlorine:

No need to store:

* sodium hypochlorite
* calcium hypochlorite
* trichlor tablets

Instead the system uses:

* electricity
* oxygen or air
* ozone generator

This reduces chemical handling risks.

7. Improved swimmer comfort

Water feels:

* softer
* less irritating
* odor-free

Reduced complaints of:

* dry skin
* itchy skin
* burning eyes
* hair damage
* faded swimsuits

 8. Reduced water replacement

Because contaminants are oxidized more completely:

* lower dissolved organic carbon
* cleaner filters
* lower total organic loading

Water quality can remain acceptable for longer, although periodic dilution is still needed to control dissolved salts and other accumulated substances.

9. Lower filter fouling

Oxidation breaks oils and proteins into smaller, more filterable compounds.

This reduces:

* greasy filter media
* clogged sand
* pressure increase

Filter cleaning intervals may be extended.


 Synergistic effects

Together, ozone nanobubbles and electrolysis can provide:

* faster microbial kill
* more complete oxidation of contaminants
* enhanced biofilm control
* improved water clarity
* reduced odor
* lower reliance on chemical additives

The combined effect is generally greater than either technology used alone because electrochemically generated reactive species enhance ozone decomposition into highly reactive radicals.

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2-7-1 Shiranui-machi, Omuta-city, Fukuoka 836-0843 JAPAN+81-944-55-3335nakashima.sales@nakashimabussan.co.jp
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2-7-1 Shiranui-machi, Omuta-city, Fukuoka 836-0843 JAPAN+81-944-55-3335nakashima.sales@nakashimabussan.co.jp